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CHEE 210: Thermodynamic Properties of Fluids

Lecture Notes

Lecture notes are provided as powerpoint files ahead of lecture times. The notes are not complete, and are meant to serve as a template only. The numbering of these powerpoint files does not refer to a specific lecture but rather the sequence in which the material will be presented.

Lectures

Notes

Topics

SVA Reference

Week 1

9 - 13 Jan

Course Intro; Dimensions, Units; Work, Energy, Heat, Systems, Processes, Cycles, Zeroth and First Law, Enthalpy, Heat Capacity

Elliptical Trainer Problem Solution

Chapters 1&2 (Mostly for Review)

Week 2
(Visuals part 1)

 

(Visuals part 2)

16 - 20 Jan

Mass and Energy Balances for Open Systems

Heating of Closed Tank with Steam Problem

PVT behaviour of pure substances, Critical Behaviour, Single phase region, Volume Expansivity,

Example from Thursday Lecture Thermal Expansion of Puddle

Chapter 2 pgs. 41 - 52

Chapter 3: Sections 3.1, ,3.2 and 3.3 (Review for most with added concepts)

Week 3

(Visuals)

23 - 27 Jan

1. Example Z calculation

2. van der Waals EOS isotherms

Isothermal Compressibility, The Ideal Gas, Ideal Gas Processes

Ideal Gas Processes ,

Chapter 3: Sections 3.4, 3.5

Week 4
(Visuals)

 

 

30 Jan - 3 Feb

1. Matlab script for calculation/integration of Cp

 

Chapters 3 : Sections
3.6, 3.7

 

Week 5
(Visuals Pt 1)

(Visuals Pt 2)

6 - 10 Feb

PVT correlations for liquids, temperature dependency of heat capacities, latent heats of pure fluids

2nd law of thermodynamics, Heat engines, Carnot cycle, Carnot efficiency

Entropy, Clausius inequality, Combination of 1st and 2nd laws

Entropy calculations,

 

 

 

 

Chapter 4, 5: Sections

4.1, 4.2, 5.1-5.6

 

 

 

Week 6
(Visuals)

13 - 17 Feb

Midterm Tuesday Feb 14

6:30-7:30 Kingston 101, 200

Closed Book

Equation Sheet (for study)

Entropy balances for open systems, ideal and lost work

 

 

Chapter 5: Sections 5.7-5.9

  READING WEEK  

Week 7

(Visuals)

 

Additional thermodynamic properties, Helmholtz energy, Gibbs energy, Maxwell equations, derivation of property equations as functions of T,P and T,V

 

Chapter 6: Sections 6.1-6.3, 6.7

Week 8

(last week's visuals cont'd))

Derivations for enthalpy and entropy

Solutions for Problem from lecture notes

Residual properties, calculation of thermodynamic properties of real fluids

Residual property calculations using Virial Eqaution of State and Cubic Equations of State

Residual property calculations using generalized correlations

Chapter 6 Section 6.4-6.5

 

 

Week 9

(Visuals Pt 1)

(Visuals Pt 2)

Thermodynamic properties from tables and graphical methods, quality.

Midterm 2 Solution

Equation Sheet

Applications to Flow Processes
Turbines, compressors, pumps

Compressor Prob 7-37 Sol'n

Chap 7 Section 7.2

Chap 7 Section 7.3

Week 10

(Visuals Pt 1)

(Visuals Pt 2)

Production of Power from Heat
Steam Power Plant (Rankine Cycle)

Factors effecting steam power plant efficiency

Chap 8 Sections
8.1 and 8.2

Week 11

(Visuals Pt 1)

(Visuals Pt 2)

Summary of steam power plant efficiency and brief overview of gas turbines and combined cycle plants

 

Same as Week 10

Chap 8 Gas Turbines (Brayton Cycle)

Week 12

Visuals

Refrigeration and Liquefaction

Chap 9

 

 


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