Robin Hutchinson: Publications

ProfessorRobin Hutchinson

Tel: (613) 533-3097
Fax: (613) 533-6637
Email: robin.hutchinson@queensu.ca

Office: Dupuis Hall 426

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Publications

2019-2020
2017-2018

2015-2016
2013-2014

2011-2012
2009-2010
2006-2008
2001-2005

DuPont Publications (1993-2000)
PhD Publications (1986-1992)
Conference Proceedings
Book Chapters





2019-2020

Heidarzadeh, N., E. G. Bygott, R. A. Hutchinson, "Exploiting Addition–Fragmentation Reactions to Produce Low Dispersity Poly(isobornyl acrylate) and Blocky Copolymers by Semibatch Radical Polymerization", Macromol. Rapid Commun. 41, in press, 2020 [more information].

Nasresfahani, A., R. A. Hutchinson, "Deterministic Approach to Estimate Functionality of Chains Produced by Radical Copolymerization in the Presence of Secondary Reactions", Macromolecules 53, 5674-5686, 2020 [More Information].

Lister, K. C., H. Kaminsky, R. A. Hutchinson, "Evaluation of a Novel Polymeric Flocculant for Enhanced Water Recovery of Mature Fine Tailings", Processes 8, 735, 2020 [More information]. Invited contribution.

Ezenwajiaku, E. H., R. Zigelstein, A. Chovancová, I. Lacík, R. A. Hutchinson, "Experimental and Modeling Investigation of Aqueous-Phase Radical Copolymerization of 2-(Methacryloyloxyethyl)trimethylammonium Chloride with Acrylic Acid", Ind. Eng. Chem. Res. 59, 3359-3374, 2020 [More information].

Heidarzadeh, N., R. A. Hutchinson, "Maximizing Macromonomer Content Produced by Starved-Feed High Temperature Acrylate/Methacrylate Semi-Batch Polymerization". Polym. Chem. 11, 2137-2146, 2020 [more information].

Russell, D. A., L. Meunier, R. A. Hutchinson, "Characterization of Degradation Products from a Hydrolytically Degradable Cationic Flocculant", Polym. Degrad. Stab. 174, 109097, 2020 [More information].

Ezenwajiaku, E. H., A. Chovancová, K. C. Lister, I. Lacík, R. A. Hutchinson, "Experimental and Modeling Investigation of Radical Homopolymerization of 2-(Methacryloyloxyethyl) Trimethylammonium Chloride in Aqueous Solution", Macromol. React. Eng. 14, 201900033, 2020 [More information].

Nasresfahani, A., L. A. Idowu, R. A. Hutchinson, "Extractable Content of Functional Acrylic Resins Produced by Radical Copolymerization: A Comparison of Experiment and Stochastic Simulation", Chem. Eng. J. 378, 122087, 2019 [More Information].

Shirali Zadeh, N., M. J. Cooze, N. R. Barr, R. A. Hutchinson, "An Efficient Process for the Cu(0)-mediated Synthesis and Subsequent Chain Extension of Poly(methyl acrylate) Macroinitiator", React. Chem. Eng. 4, 2000-2010, 2019 [More Information].

Zhang, M., R. A. Hutchinson, “Modeling the Synthesis of Butyl Methacrylate Macromonomer by Sequential ATRP-CCTP”, Macromol. React. Eng. 13, 1800062, 2019 [More information].

Hutchinson, R. A., S. Beuermann, "Critically Evaluated Propagation Rate Coefficients for Radical Polymerization: Acrylates and Vinyl Acetate (IUPAC Technical Report)", Pure Appl. Chem. 91, 1883-1888, 2019 [More information].

Idowu, L. A., R. A. Hutchinson, "Solvent Effects on Radical Copolymerization Kinetics of 2-Hydroxyethyl Methacrylate and Butyl Methacrylate", Polymers 11, 487, 2019 [More information].

Van Steenberge, P. H. M., R. A. Hutchinson, "Design of HEMA-functional Macromonomer Dispersants by Semi-batch Cobalt Chain Transfer Polymerization", AIChE J. 65, e16723, 2019 [More information].

Nikitin, A. N., I. Lacík, R. A. Hutchinson, M. Buback, G. T. Russell,  “Detection of PLP Structure for Accurate Determination of Propagation Rate Coefficients over an Enhanced Range of PLP-SEC Conditions”, Macromolecules 52, 55-71, 2019 [More information].

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2017-2018

Zhang, M., R. A. Hutchinson, “Synthesis and Utilization of Low Dispersity Acrylic Macromonomer as Dispersant for Nonaqueous Dispersion Polymerization”, Macromolecules 51, 6267-6275, 2018 [More information].

Younes, G. R., A. R. Proper, T. R. Rooney, R. A. Hutchinson, S. B. Gumfekar, J. B. P. Soares, “Structure Modifications of Hydrolytically-Degradable Polymer Flocculant for Improved Water Recovery from Mature Fine Tailings”, Ind. Eng. Chem. Res. 57, 10809-10822, 2018 [More information].

Zhang, M., R. A. Hutchinson, “Design of Acrylic Dispersants for Nonaqueous Dispersion Polymerization: The Importance of Thermodynamics”, Macromol. React. Eng. 12, 1800025, 2018 [More information].

Nasresfahani, A., R. A. Hutchinson, “Modeling the Distribution of Functional Groups in Semibatch Radical Copolymerization: An Accelerated Stochastic Approach”, Ind. Eng. Chem. Res. 57, 9407-9419, 2018 [More information].

Schier, J. E. S., M. Zhang, M. C. Grady, R. A. Hutchinson, “Modeling of Semi-batch Solution Radical Copolymerization of Butyl Methacrylate and 2-Hydroxyethyl Acrylate”, Macromol. React. Eng. 12, 1800008, 2018 [More information].

Rooney, T. R., R. A. Hutchinson, “Monomer Structure and Solvent Effects on Copolymer Composition in (Meth)acrylate Radical Copolymerization”, Ind. Eng. Chem. Res. 57, 5215-5227, 2018 [More information]. Invited contribution.

Gumfekar, S. P., T. R. Rooney, R. A. Hutchinson, J. B. P. Soares, "Dewatering Oil Sands Tailings with Degradable Polymer Flocculants", ACS Appl. Mater. Interfaces 9, 36290-36300, 2017 [More information].

Luk, S. B., R. A. Hutchinson, "Radical Copolymerization Kinetics of Bio-Renewable Butyrolactone Monomer in Aqueous Solution", Processes 5, 55, 2017 [More information]. Invited contribution, featured on issue cover.

Rooney, T. R., A. Chovancová, I. Lacík, R. A. Hutchinson, "Pulsed Laser Studies of Cationic Reactive Surfactant Propagation Kinetics", Polymer, 130, 39-49, 2017 [More information].

Schier, J. E. S., D. Cohen-Sacal, O. R. Larsen, R. A. Hutchinson, "The Effect of Hydrogen Bonding on Radical Semi-Batch Copolymerization of Butyl Acrylate and 2-Hydroxyethyl Acrylate", Polymers (MDPI), 9, 368-382, 2017 [More information]. Invited contribution.

Luk, S. B., J. Kollár, A. Chovancová, M. Mrlík, I. Lacík, J. Mosnáček, R. A. Hutchinson, "Superabsorbent Hydrogels made from Bio-sourced Butyrolactone Monomer in Aqueous Solution", Polym. Chem. 8, 1943-1952, 2017 [More information]. Featured on issue cover.

Rooney, T. R., D. Moscatelli, R. A. Hutchinson, “Polylactic Acid Macromonomer Radical Propagation Kinetics and Degradation Behaviour”, React. Chem. Eng. 2, 487-497, 2017 [More information].

Brandl, F., M. Drache, J. E. S. Schier, T. Nentwig, D. Contreras-López, E. Saldívar-Guerra, R. A. Hutchinson, S. Beuermann, "Propagation Kinetics of Isoprene – Glycidyl Methacrylate Copolymerizations Investigated via PLP-SEC", Macromol. Rapid Commun. 38, 1700105, 2017 [More information].

Schier, J. E. S., D. Cohen-Sacal, R. A. Hutchinson, "Hydrogen Bonding in Radical Solution Copolymerization Kinetics of Acrylates and Methacrylates: A Comparison of Hydroxy- and Methoxy- Functionality", Polym. Chem. 8, 6039-6049, 2017 [More information].

Yang, W., R. A. Hutchinson, “The Influence of Adding Functionality to Dispersant and Particle Core Compositions in Non-Aqueous Dispersion Polymerization”, React. Funct. Polym. 114, 31-37, 2017 [More information].

Rooney, T. R., O. Monyatsi, R. A. Hutchinson, “Polyester Macromonomer Syntheses and Radical Copolymerization Kinetics with Styrene”, Macromolecules 50, 784-795, 2017 [More information].

Barner-Kowollik, C., S. Beuermann, M. Buback, R. A. Hutchinson, T. Junkers, H. Kattner, B. Manders,  A. N. Nikitin, G. T. Russell, A. M. van Herk, "Critically Evaluated Rate Coefficients in Radical Polymerization – 8. Propagation Rate Coefficients for Vinyl Acetate in Bulk", Macromol. Chem. Phys. 218, 1600357, 2017 [More information].

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2015-2016

Nikitin, A. N., I. Lacík, R. A. Hutchinson, “A 3D Simulation Investigation of the Influence of Temperature Increases on the Accuracy of Propagation Rate Coefficients Determined by Pulsed-Laser Polymerization”, Macromolecules 49, 9320-9335, 2016 [More information].

Preusser, C., R. A. Hutchinson, "Measuring and Modeling The Peculiarities of Aqueous-Phase Radical Polymerization", Can. J. Chem. Eng. 94, 2045-2051, 2016 [More information]. Invited contribution.

Preusser, C., I.R. A. Hutchinson, "The Combined Influence of Monomer Concentration and Ionization on Acrylamide/Acrylic Acid Composition in Aqueous Solution Radical Batch Copolymerization", Macromolecules 49, 4746-4756, 2016 [More information].

Schier, J. E. S., R. A. Hutchinson, "The influence of hydrogen bonding on radical chain-growth parameters for butyl methacrylate/2-hydroxyethyl acrylate solution copolymerization", Polym. Chem. 7, 4567-4574, 2016 [More information].

Lacík, I., A. Chornocová, L. Uhelská, C. Preusser, R. A. Hutchinson, M. Buback, "PLP-SEC Studies into the Propagation Rate Coefficient of Acrylamide Radical Polymerization in Aqueous Solution", Macromolecules 49, 3244-3253, 2016 [More information].

Rooney, T. R., S. P. Gumfekar, J. B. P. Soares, R. A. Hutchinson, "Cationic Hydrolytically Degradable Flocculants with Enhanced Water Recovery for Oil Sands Tailings Remediation", Macromol. Mat. Eng. 301, 2045-2051, 2016 [More information].

Zapata-González, I., R. A. Hutchinson, K. Payne, E. Saldívar-Guerra, "Mathematical modeling of the full molecular weight distribution in ATRP techniques", AIChE J. 62, 2762-2777, 2016 [More information].

Preusser, C., A. Chornocová, I. Lacík, R. A. Hutchinson, "Modeling The Radical Batch Polymerization of Acrylamide in Aqueous Solution", Macromol. React. Eng. 10, 490-501, 2016 [More information].

Payne, K. A., J. Debling, P. Nesvadba, M. F. Cunningham R. A. Hutchinson, "NMP of styrene in batch and CSTR at elevated temperatures: Modeling experimental trends", Eur. Polym. J. 80, 186-199, 2016 [More information]. Invited contribution.

Wittenberg, N. F. G., C. Preusser, H. Kattner, M. Stach, I. Lacík, R. A. Hutchinson, M. Buback, "Modeling Acrylic Acid Radical Polymerization in Aqueous Solution", Macromol. React. Eng. 10, 95-107, 2016 [More information].

Monyatsi, O., R. A. Hutchinson, "Vinyl Pivalate Propagation Kinetics in Radical Polymerization", Macromol. Chem. Phys. 217, 51-58, 2016 [More information].

Yang, W., R. A. Hutchinson, "Investigating the Effectiveness of Reactive Dispersants in Non-Aqueous Dispersion Polymerization", Macromol. React. Eng. 10, 61-71, 2016 [More information].

Zhang, M., M. F. Cunningham R. A. Hutchinson, "Aqueous Copper(0) Mediated Reversible Deactivation Radical Polymerization of 2-Hydroxyethyl Acrylate", Polym. Chem. 6, 6509-6518, 2015 [More information].

Payne, K. A., P. Nesvadba, J. Debling, M. F. Cunningham R. A. Hutchinson, "Nitroxide-Mediated Polymerization at Elevated Temperatures", ACS Macro Lett. 4, 280-283, 2015 [More information].

Rooney, T. R., E. Mavroudakis, I. Lacík, R. A. Hutchinson, D. Moscatelli, "Pulsed Laser and Quantum Mechanics Study of n-Butyl Cyanoacrylate and Methyl Methacrylate Free-Radical Copolymerization", Polym. Chem. 6, 1594-1603, 2015 [More information].

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2013-2014

Monyatsi, O., A. N. Nikitin, R. A. Hutchinson, "Effect of Head-to-Head Addition on Vinyl Acetate Propagation Kinetics in Radical Polymerization", Macromolecules 47, 8145-8153, 2014 [More information].

Uhelská, L., D. Chorvát , R. A. Hutchinson, S. Santanakrishnan, M. Buback, I. Lacík, "Radical Propagation Kinetics of N-Vinylpyrrolidone in Organic Solvents Studied by Pulsed-Laser Polymerization– Size-Exclusion Chromatography (PLP–SEC)", Macromol. Chem. Phys. 215, 2327-2336, 2014 [More information].

Hamzehlou, S., Y. Reyes, R, A. Hutchinson, J. R. Leiza, "Copolymerization of n-Butyl Acrylate and Styrene: Terminal vs Penultimate Model", Macromol. Chem. Phys. 215, 1668-1678, 2014 [More information].

Payne, K. A., P. H. M. Van Steenberge, D. R. D'hooge, M.-F. Reyniers, G. B. Marin, R. A. Hutchinson, M. F. Cunningham, "Controlled synthesis of poly(BMA-co-BA) via ARGET ATRP: Insights and Improvement," Polym. Int. 63, 848-857, 2014 [More information]. Invited Contribution.

Zapata-González, I., R. A. Hutchinson, K. Matyjaszewski, E. Saldívar-Guerra, J. Ortiz-Cisneros, "Copolymer Composition Deviations from Mayo-Lewis Conventional Free Radical Behavior in Nitroxide Mediated Copolymerization," Macromol. Theory Simul. 23, 245-265, 2014 [More information].

Parsa, M. A., I. Kozhan, M. Wulkow, R. A. Hutchinson, "Modeling of Functional Group Distribution in Copolymerization: A Comparison of Deterministic and Stochastic Approaches," Macromol. Theory Simul. 23, 207-217, 2014 [More information].

Liang, K., T. R. Rooney, R. A. Hutchinson, "Solvent Effects on Kinetics of 2-Hydroxyethyl Methacrylate Semibatch Radical Copolymerization," Ind. Eng. Chem. Res. 53, 7296-7304, 2014 [More information].

Barner-Kowollik, C., S. Beuermann, M. Buback, P. Castignolles, B. Charleux, M. L. Coote, R. A. Hutchinson, T. Junkers, I. Lacík, G. T. Russell, M. Stach, A. M. van Herk, "Critically Evaluated Rate Coefficients in Radical Polymerization - 7. Secondary-Radical Propagation Rate Coefficients for Methyl Acrylate in Bulk," Polym. Chem. 5, 204-212, 2014 [More information].

Nikitin, A. N., R. A. Hutchinson, P. Hesse, "Determination of the Mode of Radical Termination from Pulsed Laser Polymerization Experiments in Presence of Retardation and Chain Transfer to Agent," Macromol. Chem. Phys. 214, 2670-2682, 2013 [More information].

Chan, N., J. Meuldijk, M. F. Cunningham, R. A. Hutchinson, "Continuous ARGET ATRP of Methyl Methacrylate and Butyl Acrylate in a Stirred Tank Reactor," Ind. Eng. Chem. Res. 52, 11931-11942, 2013 [More information].

Ferrari, R., T. R. Rooney, M. Lupi, P. Ubezio, R. A. Hutchinson, D. Moscatelli, "A Methyl Methacrylate - HEMA-CLn Copolymerization Investigation: from Kinetics to Bio-Applications," Macromol. Biosci. 13, 1347-1357, 2013 [More information].

Preusser, C., R. A. Hutchinson, "An in-situ NMR study of Radical Copolymerization Kinetics of Acrylamide and Non-Ionized Acrylic Acid in Aqueous Solution," Macromol. Symp. 333, 122-137, 2013 [More information].

Payne, K. A., D. R. D'hooge, P. H. M. Van Steenberge, M.-F. Reyniers, M. F. Cunningham, R. A. Hutchinson, G. B. Marin, "ARGET ATRP of Butyl Methacrylate: Utilizing Kinetic Modeling to Understand Experimental Trends," Macromolecules 46, 3828-3840, 2013[More information].

Chan, N., M. F. Cunningham, R. A. Hutchinson, "Copper Mediated Controlled Radical Polymerization in Continuous Flow Processes: Synergy between Polymer Reaction Engineering and Innovative Chemistry," J. Polym. Sci., Part A: Polym. Chem. 51, 3081-3096,  2013 [More information]. Invited Highlight.

Santanakrishnan, S., R. A. Hutchinson, "Free-Radical Polymerization of N-Vinylimidazole and Quaternized Vinylimidazole in Aqueous Solution," Macromol. Chem. Phys. 214, 1140-1146, 2013 [More information].

Wittenberg, N. F. G., R. A. Hutchinson, M. Buback, "Kinetics and Modeling of Methacrylic Acid Radical Polymerization in Aqueous Solution," Macromol. React. Eng. 7, 267-276, 2013 [More information].

Lessard, B. H., Y. Guillaneuf, M. Mathew, K. Liang, J.-L. Clement, D. Gigmes, R. A. Hutchinson, M. Marić, "Understanding the Controlled Polymerization of Methyl Methacrylate with Low Concentrations of 9-(4-Vinylbenzyl)-9H-Carbazole Comonomer by Nitroxide Mediated Polymerization: The Pivotal Role of Reactivity Ratios," Macromolecules 46, 805-813, 2013 [More information].

Moraes, R. P., R. A. Hutchinson, T. F. L. McKenna, "Small-Particle High-Solid-Content Bimodal Latexes: Highly Crosslinked Small Particles as Pseudo-Inert Nanofillers," Macromol. React. Eng. 7, 36-53, 2013 [More information].

Nerkar, M., J. A. Ramsay, B. A. Ramsay, M. Kontopoulou, R. A. Hutchinson, "Determination of Mark-Houwink Parameters and Absolute Molecular Weight of Medium-Chain-Length Poly(3-Hydroxyalkanoates)," J. Polym. Environ. 21, 24-29, 2013 [More information].

Liang, K., R. A. Hutchinson, "Solvent Effects in Semibatch Free Radical Copolymerization of 2-Hydroxyethyl Methacrylate and Styrene at High Temperatures," Macromol. Symp. 325-326, 203-212, 2013 [More information].

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2011-2012

Mavroudakis, E., K. Liang, D. Moscatelli, R. A. Hutchinson, "A Combined Computational and Experimental Study on the Free Radical Copolymerization of Styrene and Hydroxyethyl Acrylate," Macromol. Chem. Phys. 213, 1706-1713, 2012 [More information].

Santanakrishnan, S., M. Stach, I. Lacik, R. A. Hutchinson, "Aqueous-Phase Copolymerization of N-vinylpyrrolidone and N-vinylformamide," Macromol. Chem. Phys. 213, 1330-1338, 2012 [More information].

Chan, N., M. F. Cunningham, R. A. Hutchinson, "Copper mediated controlled radical polymerization of methyl acrylate in the presence of ascorbic acid in a continuous tubular reactor," Polym. Chem. 3, 1322-1333, 2012 [More information].

Payne, K., M. F. Cunningham, Robin A. Hutchinson, "ARGET ATRP of BMA and BA: Exploring Limitations at Low Copper Levels,"ACS Symp. Ser. 1100, 183-202, 2012 [More information].

Smeets, N. M. B., R. A. Hutchinson, T. F. McKenna, "Determination of the Critical Chain Length of Oligomers in Dispersion Polymerization," ACS Macro Lett. 1, 171-174, 2012 [More information].

Chan, N., M. F. Cunningham, R. A. Hutchinson, "Continuous Controlled Radical Polymerization of Methyl Acrylate with Copper Wire in a CSTR," Polym. Chem. 3, 486-497, 2012 [More information].

Moraes, M., I. Zavecs, P. Lauvernier, N. M. B. Smeets, R. A. Hutchinson, T. F. McKenna, "The Effect of Cosurfactants and the Initiator Concentration on the Polymer to Surfactant Concentration in Nanolatex," J. Polym. Chem. Part A: Polym. Chem. 50, 944-956, 2012 [More information].

Ferrari, R., Y. Yu, M. Morbidelli, R. A. Hutchinson, D. Moscatelli, , "Caprolactone-Based Macromonomers Suitable for Biodegradable Nanoparticles Synthesis through Free Radical Polymerization," Macromolecules 44, 9205-9212, 2011 [More information].

Cockburn, R. A., T. F. L. McKenna, R. A. Hutchinson, "A Study of Particle Nucleation in Dispersion Copolymerization of Methyl Methacrylate," Macromol. React. Eng. 5, 405-417, 2011 [More information].

Liang, K., R. A. Hutchinson, J. Barth, S. Samrock, M. Buback, "Reduced branching in poly(butyl acrylate) via solution radical polymerization in n-butanol," Macromolecules 44, 5843-5845, 2011 [More information].

Cockburn, R. A., R. Siegmann, K. A. Payne, S. Beuermann, T. F. L. McKenna, R. A. Hutchinson, "Free Radical Copolymerization Kinetics of gamma-Methyl-alpha-Methylene-gamma-Butyrolactone (MeMBL)," Biomacromolecules 12, 2319-2326, 2011 [More information].

Liang, K., R. A. Hutchinson, "The Effect of Hydrogen Bonding on Intramolecular Chain Transfer in Polymerization of Acrylates,"Macromol. Rapid Commun. 32, 1090-1095, 2011 [More information].

Schrooten, J., M. Buback, P. Hesse, R. A. Hutchinson, I. Lacik, "Termination Kinetics of 1-Vinylpyrrolidin-2-one Radical Polymerization in Aqueous Solution," Macromol. Chem. Phys. 212, 1400-1409, 2011 [More information].

Chan, N., M. F. Cunningham, R. A. Hutchinson, "Continuous Controlled Radical Polymerization of Methyl Acrylate in a Copper Tubular Reactor," Macromol. Rapid Commun. 32, 604-609, 2011 [More information].

Nikitin, A. N., R. A. Hutchinson, M. Buback, P. Hesse, "A Novel Approach for Investigation of Chain Transfer Events by Pulsed Laser Polymerization," Macromol. Chem. Phys. 212, 699-707, 2011 [More information].

Santanakrishnan, S., R. A. Hutchinson, L. Uncova, M. Stach, I. Lacik, M. Buback, "Influence of Propagation Rate Coefficient on the Kinetic Behavior of Water-Soluble Vinyl Monomers," Macromol. Symp. 302, 216-223, 2011 [More information].

Wang, W., R. A. Hutchinson, "A Comprehensive Kinetic Model for High Temperature Free-Radical Production of Styrene/Methacrylate/Acrylate Resins," AIChE J 57, 227-238, 2011 [More information].

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2009-2010

Liang, K., R. A. Hutchinson, "Solvent Effects on Free-Radical Copolymerization Propagation Kinetics of Styrene and Methacrylates," Macromolecules 43, 6311-6320, 2010 [More information].

Wang, W., R. A. Hutchinson, "Free-Radical Acrylic Polymerization Kinetics at Elevated Temperatures," Chem. Eng. Technol. 33, 1745-1753, 2010 [More information].

Santanakrishnan, S., R. A. Hutchinson, M. Stach, I. Lacik, J. Schrooten, P. Hesse, M. Buback, "Kinetics and Modeling of N-vinyl Pyrrolidone Free Radical Polymerization," Macromol. React. Eng. 4, 499-509, 2010 [More information].

Nikitin, A. N., R. A. Hutchinson, W. Wang, G. A. Kalfas, J. R. Richards, C. Bruni, "Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates, 5 - Consideration of Solution Polymerization up to High Temperatures,"Macromol. React. Eng. 4, 691-706, 2010 [More information].

Chan, N., M. F. Cunningham, R. A. Hutchinson, "Reducing ATRP Catalyst Concentration in Batch, Semibatch and Continuous Reactors," Macromol. React. Eng. 4, 369-380, 2010 [More information].

Dossi, M., K. Liang, R. A. Hutchinson, D. Moscatelli, "An Investigation of Free-Radical Copolymerization Propagation Kinetics of Vinyl Acetate and Methyl Methacrylate," J. Phys. Chem. B 114, 4213-4222, 2010 [More information].

Cockburn, R. A., T. F. L. McKenna, R. A. Hutchinson, "An Investigation of Free Radical Copolymerization Kinetics of the Bio-Renewable Monomer γ-Methyl-α-Methylene-γ-Butyrolactone with Methyl Methacrylate and Styrene," Macromol. Chem. Phys. 211, 501-509, 2010 [More information].

Stach, M., P. Kasak, I. Lacik, D. Chorvat, Jr., A. J. Saunders, S. Santanakrishnan, R. A. Hutchinson, "Free-Radical Propagation Kinetics of N-vinyl Formamide in Aqueous Solution studied by PLP−SEC," Macromol. Chem. Phys. 211, 580-593, 2010 [More information].

Moraes, R. P., R. A. Hutchinson, T. F. L. McKenna, "The Production of High Polymer to Surfactant Microlatexes," J. Polym. Chem. Part A: Polym. Chem. 48, 48-54, 2010 [More information].

Wang, W., R. A. Hutchinson, "High Temperature Semibatch Free Radical Copolymerization of Styrene and Butyl Acrylate,"Macromol. Symp. 289, 33-42, 2010 [More information].

Perea, L. F. T., O. E. Okorafo, R. A. Hutchinson, M. Guay, "Development of On-line Optimization-Based Control Strategies for a Starved-Feed Semibatch Copolymerization Reactor," Control Engineering Practice 18, 131-139, 2010 [More information].

Liang, K., M. Dossi, D. Moscatelli, R. A. Hutchinson, "An Investigation of Free-Radical Copolymerization Propagation Kinetics of Styrene and 2-Hydroxyethyl Methacrylate," Macromolecules 42, 7763-7769, 2009 [More information].

Wang, W., A. N. Nikitin, R. A. Hutchinson, "Consideration of Macromonomer Reactions in Buty Acrylate Free Radical Polymerization," Macromol. Rapid Commun. 30, 2022-2027, 2009 [More information].

Wang, W., R. A. Hutchinson, "Evidence of Scission Products from Peroxide-Initiated Higher Temperature Polymerization of Alkyl Methacrylates," Macromolecules 42, 4910-4913, 2009 [More information].

Nikitin, A. N., R. A. Hutchinson, "Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates, 4 - Consideration of Penultimate Effect," Macromol. Rapid Commun. 30, 1981-1988, 2009 [More information].

Chan, N., S. Boutti, M. F. Cunningham, R. A. Hutchinson, "Continuous Atom Transfer Radical Polymerization with Low Catalyst Concentration in a Tubular Reactor," Macromol. React. Eng. 3, 222-231, 2009 [More information].

Nikitin, A. N., R. A. Hutchinson, G. A. Kalfas, J. R. Richards, C. Bruni, "Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates, 3 - Consideration of Solution Polymerization up to High Conversions," Macromol. Theory Simul. 18, 247-258, 2009 [More information].

Wang, W., R. A. Hutchinson, M. C. Grady, "Study of Butyl Methacrylate Depropagation Behavior using Batch Experiments in Combination with Modeling," Ind. Eng. Chem. Res. 48, 4810-4816, 2009 [More information].

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2006-2008

Wang, W., R. A. Hutchinson, "PLP/SEC/NMR Study of Free Radical Copolymerization of Styrene and Glycidyl Methacrylate,"Macromolecules 41, 9011-9018, 2008 [More information].

Buback, M., P. Hesse, R. A. Hutchinson, P. Kasak, I. Lacik, M. Stach, I. Utz, "Kinetics and Modeling of Free-Radical Batch Polymerization of Non-ionized Methacrylic Acid in Aqueous Solution," Ind. Eng. Chem. Res. 47, 8197-8204, 2008 [More information].

Chan, N., M. F. Cunningham, R. A. Hutchinson, "ARGET ATRP of Methacrylates and Acrylates with Stoichiometric Ligand to Copper Ratios," Macromol. Chem. Phys. 209, 1797-1805, 2008 [More information].

Asteasuain, M., M. Soares, M. K. Lenzi, R. A. Hutchinson, M. F. Cunningham, A. Brandolin, J. C. Pinto, C. Sarmoria, "Living Radical Polymerization in Tubular Reactors: Process Optimization for Tailor-Made Molecular Weight Distributions," Macromol. React. Eng.2, 414-421, 2008 [More information].

Nikitin, A. N., M. C. Grady, G. A. Kalfas, R. A. Hutchinson, , "Investigation of Catalytic Chain Transfer Copolymerization of Methacrylates," Macromol. React. Eng. 2, 422-435, 2008 [More information].

Stach, M., I. Lacik, D. Chorvat Jr, M. Buback, P. Hesse, R. A. Hutchinson, L. Tang, "Propagation rate coefficient for radical polymerization of N-vinyl pyrrolidone in aqueous solution obtained by PLP-SEC," Macromolecules 41, 5174-5185, 2008 [More information].

Beuermann, S., M. Buback, P. Hesse, R. A. Hutchinson, S. Kukuckova, I. Lacik, "Termination Kinetics of the Free-Radical Polymerization of Non-Ionized Methacrylic Acid in Aqueous Solution," Macromolecules 41, 3513-3520, 2008 [More information].

Wang, W., R. A. Hutchinson, "Recent Advances in the Study of High Temperature Free Radical Acrylic Solution Copolymerization,"Macromol. React. Eng. 2, 199-214, 2008 [More information].

Wang, W., R. A. Hutchinson, "High Temperature Semibatch Free Radical Copolymerization of Dodecyl Methacrylate and Styrene,"Macromol. Symp. 261, 64-73, 2008 [More information].

Mueller, M., M. F. Cunningham, R. A. Hutchinson, "Continuous Atom Transfer Radical Polymerization in a Tubular Reactor,"Macromol. React. Eng. 2, 31-36, 2008 [More information].

Fu, Y., M. F. Cunningham, R. A. Hutchinson, "Semibatch Atom Transfer Radical Copolymerization of Styrene and Butyl Acrylate,"Macromol. Symp. 259, 151-163, 2007 [More information].

Nikitin, A. N., R. A. Hutchinson, M. Buback, P. Hesse, "Determination of Intramolecular Chain Transfer and Midchain Radical Propagation Rate Coefficients for Butyl Acrylate by Pulsed Laser Polymerization," Macromolecules 40, 8631-8641, 2007 [More information].

Li, D., R. A. Hutchinson, "Penultimate Propagation Kinetics of Butyl Methacrylate, Butyl Acrylate, and Styrene Terpolymerization,"Macromol. Rapid Commun. 28, 1213-1218, 2007 [More information].

Fu, Y., A. Mirzaei, M. F. Cunningham, R. A. Hutchinson, "Atom-Transfer Radical Batch and Semibatch Polymerization of Styrene,"Macromol. React. Eng. 1, 425-439, 2007 [More information].

Nikitin, A. N., R. A. Hutchinson, "Determination of the Mode of Free Radical Termination from Pulsed Laser Polymerization Experiments," Macromol. Theory Simul. 16, 29-42, 2007 [More information].

Fu, Y., M. F. Cunningham, R. A. Hutchinson, "Modeling of Nitroxide Mediated Semibatch Radical Polymerization," Macromol. React. Eng. 1, 243-252, 2007 [More information].

Bebe, S., X. Yu, R. A. Hutchinson, L. J. Broadbelt, "Estimation of Free Radical Polymerization Rate Coefficients Using Computational Chemistry," Macromol. Symp. 243, 179-189, 2006 [More information].

Li, D., R. A. Hutchinson, "High Temperature Semibatch Free Radical Copolymerization of Butyl Methacrylate and Styrene,"Macromol. Symp. 243, 24-34, 2006 [More information].

Li, N., A. S. Cho, L. J. Broadbelt, R. A. Hutchinson, "Low Conversion 4-Acetoxystyrene Free-Radical Polymerization Kinetics determined by Pulsed-Laser and Thermal Polymerization," Macromol. Chem. Phys. 207, 1429-1438, 2006 [More information].

Li, D., N. Li, R. A. Hutchinson, "High Temperature Free Radical Copolymerization of Styrene and Butyl Methacrylate with Depropagation and Penultimate Kinetic Effects," Macromolecules 39, 4366-4373, 2006 [More information].

Nikitin, A. N., R. A. Hutchinson, "Stationary Free Radical Polymerization in the Presence of Intramolecular Transfer to Polymer: 2. Improved Consideration of Termination," Macromol. Theory Simul. 15, 128-136, 2006 [More information].

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2001-2005

Li, D., J. R. Leiza, R. A. Hutchinson, "High Temperature Free Radical Copolymerization with Depropagation and Penultimate Kinetic Effects," Macromol. Theory Simul. 14, 554-559, 2005 [More information].

Wang, Y., R. A. Hutchinson, M. F. Cunningham, "A Semibatch Process for Nitroxide-Mediated Polymerization," Macromol. Mat. Eng. 290, 230-241, 2005 [More information].

Li, D., M. C. Grady, M.C., R. A. Hutchinson, "High Temperature Semibatch Free-Radical Copolymerization of Butyl Methacrylate and Butyl Acrylate," Ind. Eng. Chem. Res. 44, 2506-2517, 2005 [More information].

Nikitin, A. N., R. A. Hutchinson, "Stationary Free Radical Polymerization in the Presence of Intramolecular Transfer to Polymer,"Macromolecules 38, 1581-1590, 2005 [More information].

Asua, J. M., S. Beuermann, M. Buback, P. Castignolles, B. Charleux, R. G. Gilbert, R. A. Hutchinson, J. R. Leiza, A. N. Nikitin, J.-P. Vairon, A. M. van Herk, "Critically Evaluated Rate Coefficients for Free-Radical Polymerization: 5. Propagation Rate Coefficient for Butyl Acrylate," Macromol. Chem. Phys. 205, 2151-2160, 2004 [More information].

Peck, A.N.F., R. A. Hutchinson, "Secondary Reactions in the High Temperature Free Radical Polymerization of Butyl Acrylate,"Macromolecules 37, 5944-5951, 2004 [More information].

Hutchinson, R. A., P. J. McLellan, J. O. Ramsay, H. Sulieman, D. W. Bacon, "Investigating the Impact of Operating Parameters on Molecular Weight Distributions using Functional Regression," Macromol. Symp. 204, 495-508, 2004 [More information].

Ghiass, M., R. A. Hutchinson, "Simulation of Free Radical High Pressure Copolymerization in a Multizone Autoclave: Compartment Model Investigation," Macromol. Symp. 204, 443-456, 2004 [More information].

Ray, W. H., J. B. P. Soares, R. A. Hutchinson, "Polymerization Reaction Engineering: Past, Present, and Future," Macromol. Symp.204, 1-14, 2004 [More information].

Monwar, M., S. J. Oh, P. J. Rinaldi, E. F. McCord, R. Hutchinson, M. Buback, H. Latz, "Characterization of n-Butyl Acrylate Triads in Poly(n-butyl acrylate-co-carbon monoxide-co-ethylene) by Isotopic Labeling and Two-Dimensional NMR," Anal. Bioanal. Chem.378, 1414-1427, 2004 [more information].

Ghiass, M., R. A. Hutchinson, "Simulation of Free Radical High Pressure Copolymerization in a Multizone Autoclave: Model Development and Application," Polym. React. Eng. 11, 989-1015, 2003 [more information].

Beuermann, S., M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, M. Kamachi, I. Lac k, G. T. Russell, "Critically Evaluated Rate Coefficients for Free-Radical Polymerization: 4. Propagation Rate Coefficients for Methacrylates with Cyclic Ester Groups," Macromol. Chem. Phys. 204, 1338-1350, 2003 [More information].

Grady, M. C., Simonsick, W. J., Hutchinson, R. A., "Studies of Higher Temperature Polymerization of n-Butyl Methacrylate and n-Butyl Acrylate," Macromol. Symp. 182, 149-168, 2002 [More information].

Hutchinson, R. A., "Modeling of Chain Length and Long-Chain Branching Distributions in Free-Radical Polymerization," Macromol. Theory Simul. 10, 144-157, 2001 [More information].

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Publications while at DuPont (1993-2000)

Beuermann, S., M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, B. L. Klumperman, G. T. Russell, "Critically Evaluated Rate Coefficients for Free-Radical Polymerization: 3. Propagation Rate Coefficient for Alkyl Methacrylates," Macromol. Chem. Phys. 201, 1355-1364, 2000 [More information].

Hutchinson, R. A., D. A. Paquet, Jr., S. Beuermann, and J. H. McMinn, "Investigation of Methacrylate Free-Radical Depropagation Kinetics by Pulsed-Laser Polymerization," Ind. Eng. Chem. Res. 37, 3567-3574, 1998 [More information].

Hutchinson, R. A., Beuermann, S., D. A. Paquet, Jr., J. H. McMinn, C. Jackson, "Determination of Free-Radical Propagation Rate Coefficients for Cycloalkyl and Functional Methacrylates by Pulsed-Laser Polymerization," Macromolecules 31, 1542-1547, 1998 [More information].

Hutchinson, R. A., Beuermann, S., D. A. Paquet, Jr., and J. H. McMinn, "Determination of Free-Radical Propagation Rate Coefficients for Alkyl Methacrylates by Pulsed-Laser Polymerization," Macromolecules 30, 3490-3493, 1997 [More information].

Beuermann, S., M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, O. F. Olaj, G. T. Russell, J. Schweer, and A. M. van Herk, "Critically Evaluated Rate Coefficients for Free-Radical Polymerization: 2. Propagation Rate Coefficient for Methyl Methacrylate,"Macromol. Chem. Phys. 198, 1545-1560, 1997 [More information].

Hutchinson, R. A., D. A. Paquet, Jr., J. H. McMinn, S. Beuermann, and C. Jackson, "A Pulsed-Laser Study of Penultimate Copolymerization Propagation Kinetics for Methyl Methacrylate/n-Butyl Acrylate," Ind. Eng. Chem. Res. 36, 1103-1113, 1997 [More information].

McCord, E. F., W. H. Shaw, Jr., and R. A. Hutchinson, "Short-Chain Branching Structures in Ethylene Copolymers Prepared by High-Pressure Free-Radical Polymerization: an NMR Analysis," Macromolecules 30, 246-256, 1997 [More information].

Beuermann, S., D. A. Paquet, Jr., J. H. McMinn, and R. A. Hutchinson, "Propagation Kinetics of Methacrylic Acid Studied by Pulsed-Laser Polymerization," Macromolecules 30, 194-197, 1997 [More information].

Beuermann, S., R. A. Hutchinson, D. A. Paquet, Jr., and J. H. McMinn, "Determination of Free-Radical Propagation Rate Coefficients of Butyl, 2-Ethylhexyl and Dodecyl Acrylates by Pulsed-Laser Polymerization," Macromolecules 29, 4206-4215, 1996 [More information].

Buback, M., R. G. Gilbert, R. A. Hutchinson, B. Klumperman, F.-D. Kuchta, B. G. Manders, K. F. O'Driscoll, G. T. Russell, J. Schweer, "Critically Evaluated Rate Coefficients for Free-Radical Polymerization: 1. Propagation Rate Coefficient for Styrene," Macromol. Chem. Phys. 196, 3267-3280, 1995 [More information].

Hutchinson, R. A., D. A. Paquet, Jr., and J. H. McMinn, "The Determination of Free-Radical Chain-Transfer Rate Coefficients by Pulsed-Laser Polymerization," Macromolecules 28, 5655-5663, 1995 [more information].

Hutchinson, R. A., D. A. Paquet, Jr., J. H. McMinn, and R. E. Fuller, "Measurement of Free-Radical Propagation Rate Coefficients for Ethyl, Butyl and iso-Butyl Methacrylates by Pulsed-Laser Polymerization," Macromolecules 28, 4023-4028, 1995 [more information].

Hutchinson, R. A., J. R. Richards, and M. T. Aronson, "Determination of Propagation Rate Coefficients by Pulsed-Laser Polymerization with Rapid Chain Growth: Vinyl Acetate," Macromolecules 27, 4530-4537, 1994 [more information].

Hutchinson, R. A., M. T. Aronson, and J. R. Richards, "Analysis of Pulsed-Laser-Generated Molecular Weight Distributions for the Determination of Propagation Rate Coefficients," Macromolecules 26, 6410-6415, 1993 [more information].

Hutchinson, R. A., "Modeling of Free-Radical Polymerization Kinetics with Crosslinking for Methyl Methacrylate /Ethylene Glycol Methacrylate," Polym. React. Eng. 1, 521-577, 1993 [more information].

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PhD Publications (1986-1992)

Hutchinson, R. A., C. M. Chen and W. H. Ray, "Polymerization of Olefins Through Heterogeneous Catalysis - X. Modeling of Particle Growth and Morphology," J. Appl. Polym. Sci. 44, 1389, 1992 [More information].

Hutchinson, R. A. and W. H. Ray, "Polymerization of Olefins Through Heterogeneous Catalysis - the Effect of Condensation Cooling on Particle Ignition," J. Appl. Polym. Sci. 43, 1387, 1991 [More information].

Hutchinson, R. A. and W. H. Ray, "Polymerization of Olefins Through Heterogeneous Catalysis - IX. Experimental Study of Propylene Polymerization over a High Activity MgCl2 -Supported Ti Catalyst," J. Appl. Polym. Sci. 43, 1271, 1991 [More information].

Hutchinson, R. A. and W. H. Ray, "Polymerization of Olefins Through Heterogeneous Catalysis - VIII. Monomer Sorption Effects," J. Appl. Polym. Sci. 41, 51, 1990 [More information].

Hutchinson, R. A. and W. H. Ray, "Polymerization of Olefins Through Heterogeneous Catalysis - VII. Particle Ignition and Extinction Phenomena," J. Appl. Polym. Sci. 34, 657, 1987 [More information].

Floyd, S., R. A. Hutchinson and W. H. Ray, "Polymerization of Olefins Through Heterogeneous Catalysis - V. Gas-Liquid Mass Transfer Limitations in Liquid Slurry Reactors," J. Appl. Polym. Sci. 32, 5451, 1986 [More information].

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Books (Chapters)

Hutchinson, R. A., "Radical Polymerization Kinetics," in Elsevier Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, November, J. Reedijk, ed(s)., Elsevier, Waltham, MA, 2013, doi: 10.1016/B978-0-12-409547-2.05416-0, [More information].

Hutchinson, R. A., A. Penlidis, "Homogeneous Free Radical Polymerization," (p. 118-178) in Polymer Reaction Engineering, August, J. M. Asua, ed(s)., Blackwell Publishing Inc., Oxford UK, 2007.

Hutchinson, R. A., "Homogeneous Free Radical Polymerization," Ch. 4, (p. 153-211) in Handbook of Polymer Reaction Engineering, Wiley-VCH, Weinheim, 2005.

Cunningham, M. F., R. A. Hutchinson, "Industrial Applications and Processes," Ch. 7, (p. 333-359) in High Polymer Series: Free-radical Polymerization, T. P. Davis and K. Matyjaszewski, ed(s)., Wiley Interscience, New York, 2002.

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Conference Proceedings

Fu, Y., M. F. Cunningham, R. A. Hutchinson, "Controlled Radical Semibatch Polymerization for the Production of Solvent-Borne Coatings Resins," pp. 467-472, Vol. 138, No. VCH Verlags., 2004.

Wang, Y., F. Naulet, M. F. Cunningham, R. A. Hutchinson, "Nitroxide-Mediated Semibatch Polymerization for the Production of Low-Molecular Weight Solvent-Borne Coatings Resins," ACS Symp. Ser., pp. 466-480, Vol. 854, 2003.

Hutchinson, R. A., and R. E. Fuller, "Modeling and Measurement of High Pressure Ethylene Polymerization Long-Chain Branching and Molecular Weight Distributions," pp. 35-47, Vol. 134, No. VCH Verlags., 1998.

Hutchinson, R. A., D. A. Paquet, Jr., J. H. McMinn, S. Beuermann, R. E. Fuller and C. Jackson, "The Application of Pulsed-Laser Methods for the Determination of Free-Radical Polymerization Rate Coefficients," pp. 467-492, Vol. 131, No. VCH Verlags., 1995.

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